I don't have any firsthand experience in commercial real estate (CRE) yet but I've been looking into it. Something I can offer you is relevant podcasts:
1. The Old Capital guys are lenders based in DFW and offer a bunch of information that you might find useful, including their whitepaper and checklist, not to mention the podcast itself which features many CRE syndicators: www.oldcapitalpodcast.com
2. Tom Wilson's Real Estate Power Investing podcast is great. He is a very active large-deal syndicator based in the California Bay Area. He focuses on CRE and gives a lot of good advice, plus he has great people on his show: www.tomwilsonproperties.com/radio-show
3. Bull Realty is based in Atlanta and they have a good CRE show as well: www.commercialrealestateshow.com
If you want to really know how to make a syndication deal work, you might consider participating with an experienced syndicator as a passive investor and asking lots of questions, or perhaps offering to help, to learn what a pro would do so you can emulate it later.
My perception is that most people who get into sponsoring syndication deals start pretty small and do progressively bigger deals. Having a good track record gives lenders and syndication partners confidence and unlocks a lot of doors.
I'd be interested if you could find detailed how-to information on becoming a syndicate sponsor, how to properly write an NOI, etc. If you are really serious and in a position to do it, I think if you talk to a good lender or broker with experience working with sponsors they will likely be able to give you lots of good advice.