Keep in mind the financial resources do not have to be yours, they just have to be money you have access to; not just banks but also friends family, hard money lenders etc. 

Would you suggest I try to qualify for financing while still married, (obviously I would agree and sign whatever that husband would not be responsible), or do you suggest that I wait until afterwards to avoid any legal/financial complications or wait and find a way to use OPM?

A new LLC has no financial history, and so won't qualify for a loan on its own.It is possible to get a true non-recourse business loan.  

Your best option would be to find a place for her to rent that she can afford with out needing your financial assistance , one you do not own, and rent your own place to a tenant.

If you trust your CPA already, it may be better to let them continue to make tax decisions and instead have a bookkeeper that keeps all your financial ducks in a row on a monthly basis.

Don’t ever let any financial professional tell you that “you don’t have a choice.”

Still have a great job for a great company (recently promoted even) but I have come to the realization that I'm working my hiney off to make someone else financially free instead of "minding MY business".

How often will you receive financials? 

Also to meet fellow real estate investors in the 860 area as well as nationally.My goal is to achieve financial freedom through real estate and hopefully in 5 years get involved in some commercial real estate.

My name is Daniel Green and I am a 16-year-old who plans to use investing in buy and hold real estate to not only put me on the path to financial freedom but to accelerate it.